Thermal conduction is the transfer of internal energy by microscopic collisions of particles and movement of electrons within a body. The colliding particles, which include molecules, atoms and electrons, transfer disorganized microscopic kinetic and potential energy, jointly known as internal energy. Conduction takes place in all phases: solid, liquid, and gas. The rate at which energy is conducted as the heat between two bodies depends on the temperature difference (and hence temperature gradient) between the two bodies and the properties of the conductive interface through which the heat is transferred.

Heat spontaneously flows from a hotter to a colder body. For example, heat is conducted from the hotplate of an electric stove to the bottom of a saucepan in contact with it. In the absence of an opposing external driving energy source, within a body or between bodies, temperature differences decay over time, and thermal equilibrium is approached, temperature becoming more uniform.

The law of heat conduction, also known as Fourier's law, states that the rate of heat transfer through a material is proportional to the negative gradient in the temperature and to the area, at right angles to that gradient, through which the heat flows. The thermal conductivity, k is often treated as a constant.

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Thumbnail: Thermal conduction and Thermal conductivity